An environmentally benign and practical synthesis of sugar orthoesters promoted by potassium fluoride

Shinichiro Shoda; Masashi Moteki; Ryuko Izumi; Masato Noguchi

doi:10.1016/j.tetlet.2004.09.175

An environmentally benign and practical synthesis of sugar orthoesters promoted by potassium fluoride

Shinichiro Shoda, Masashi Moteki, Ryuko Izumi, Masato Noguchi

ENG - Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

An extremely practical method for synthesis of sugar orthoesters has been developed without using any organic amines or heavy metals as additives. Various sugar orthoesters were prepared in good yields by the reaction of an acylated glycosyl bromide and an alcohol in the presence of potassium fluoride.

Original language	English
Pages (from-to)	8847-8848
Number of pages	2
Journal	Tetrahedron Letters
Volume	45
Issue number	48
DOIs	https://doi.org/10.1016/j.tetlet.2004.09.175
Publication status	Published - 2004 Nov 22

Keywords

Glycosyl bromides
Potassium fluoride
Sugar orthoesters

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2004.09.175

Cite this

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title = "An environmentally benign and practical synthesis of sugar orthoesters promoted by potassium fluoride",

abstract = "An extremely practical method for synthesis of sugar orthoesters has been developed without using any organic amines or heavy metals as additives. Various sugar orthoesters were prepared in good yields by the reaction of an acylated glycosyl bromide and an alcohol in the presence of potassium fluoride.",

keywords = "Glycosyl bromides, Potassium fluoride, Sugar orthoesters",

author = "Shinichiro Shoda and Masashi Moteki and Ryuko Izumi and Masato Noguchi",

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T1 - An environmentally benign and practical synthesis of sugar orthoesters promoted by potassium fluoride

AU - Shoda, Shinichiro

AU - Moteki, Masashi

AU - Izumi, Ryuko

AU - Noguchi, Masato

PY - 2004/11/22

Y1 - 2004/11/22

N2 - An extremely practical method for synthesis of sugar orthoesters has been developed without using any organic amines or heavy metals as additives. Various sugar orthoesters were prepared in good yields by the reaction of an acylated glycosyl bromide and an alcohol in the presence of potassium fluoride.

AB - An extremely practical method for synthesis of sugar orthoesters has been developed without using any organic amines or heavy metals as additives. Various sugar orthoesters were prepared in good yields by the reaction of an acylated glycosyl bromide and an alcohol in the presence of potassium fluoride.

KW - Glycosyl bromides

KW - Potassium fluoride

KW - Sugar orthoesters

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DO - 10.1016/j.tetlet.2004.09.175

M3 - Article

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VL - 45

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EP - 8848

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 48

ER -

An environmentally benign and practical synthesis of sugar orthoesters promoted by potassium fluoride

Abstract

Keywords

ASJC Scopus subject areas

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