An elusive phase transition in Na2RbC60

Luigi Cristofolini; Konstantinos Kordatos; Gerard A. Lawless; Kosmas Prassides; Katsumi Tanigaki; Martin P. Waugh

doi:10.1039/a606908h

An elusive phase transition in Na₂RbC₆₀

Luigi Cristofolini, Konstantinos Kordatos, Gerard A. Lawless, Kosmas Prassides, Katsumi Tanigaki, Martin P. Waugh

Advanced Institute for Materials Research (AIMR)

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The ternary Na₂RbC₆₀ fulleride is studied by variable-temperature solid-state ¹³C and ²³Na NMR spectroscopies; in addition to the well known orientational order/disorder transition, a phase transformation to a low-symmetry phase which likely contains bonded C₆₀^3- moieties is identified at low temperature for the first time.

Original language	English
Pages (from-to)	375-376
Number of pages	2
Journal	Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/a606908h
Publication status	Published - 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "An elusive phase transition in Na2RbC60",

abstract = "The ternary Na2RbC60 fulleride is studied by variable-temperature solid-state 13C and 23Na NMR spectroscopies; in addition to the well known orientational order/disorder transition, a phase transformation to a low-symmetry phase which likely contains bonded C603- moieties is identified at low temperature for the first time.",

author = "Luigi Cristofolini and Konstantinos Kordatos and Lawless, {Gerard A.} and Kosmas Prassides and Katsumi Tanigaki and Waugh, {Martin P.}",

year = "1997",

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T1 - An elusive phase transition in Na2RbC60

AU - Cristofolini, Luigi

AU - Kordatos, Konstantinos

AU - Lawless, Gerard A.

AU - Prassides, Kosmas

AU - Tanigaki, Katsumi

AU - Waugh, Martin P.

PY - 1997

Y1 - 1997

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AB - The ternary Na2RbC60 fulleride is studied by variable-temperature solid-state 13C and 23Na NMR spectroscopies; in addition to the well known orientational order/disorder transition, a phase transformation to a low-symmetry phase which likely contains bonded C603- moieties is identified at low temperature for the first time.

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U2 - 10.1039/a606908h

DO - 10.1039/a606908h

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JO - Chemical Communications

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SN - 1359-7345

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An elusive phase transition in Na₂RbC₆₀

Abstract

ASJC Scopus subject areas

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