An electron-transfer ferromagnet with Tc = 107 K based on a three-dimensional [Ru2]2/TCNQ system

Natsuko Motokawa, Hitoshi Miyasaka, Masahiro Yamashita, Kim R. Dunbar

Research output: Contribution to journalArticlepeer-review

108 Citations (Scopus)

Abstract

Electron-transfer makes a magnet: 2:1 assembly of [Ru2 II,IIL4] paddlewheel complexes and BDTA-TCNQ yielded a new structural type of electron-transfer system with a three-dimensional network structure which exhibits a long-range ferromagnetic transition at Tc = 107 K (see depicted χ vs T curve and inset view of structure along the a axis). L = m-fluorobenzoate, BTDA-TCNQ = bis(1,2,5-thiadiazolo) tetracyanoquinodimethane.

Original languageEnglish
Pages (from-to)7760-7763
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number40
DOIs
Publication statusPublished - 2008 Sep 22

Keywords

  • Carboxylate ligands
  • Electron transfer
  • Magnetic properties
  • Quinodimethanes
  • Ruthenium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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