An efficient method for the alkynylation of oxiranes using alkynyl boranes

Masahiko Yamaguchi; Ichiro Hirao

doi:10.1016/S0040-4039(00)81416-1

An efficient method for the alkynylation of oxiranes using alkynyl boranes

Masahiko Yamaguchi, Ichiro Hirao

Research output: Contribution to journal › Article › peer-review

478 Citations (Scopus)

Abstract

Alkynyl boranes, generated in situ from lithium acetylides and boron trifluoride etherate, were found to react with oxiranes under mild reaction conditions to afford β-hydroxyacetylenes in high yields.

Original language	English
Pages (from-to)	391-394
Number of pages	4
Journal	Tetrahedron Letters
Volume	24
Issue number	4
DOIs	https://doi.org/10.1016/S0040-4039(00)81416-1
Publication status	Published - 1983
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)81416-1

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title = "An efficient method for the alkynylation of oxiranes using alkynyl boranes",

abstract = "Alkynyl boranes, generated in situ from lithium acetylides and boron trifluoride etherate, were found to react with oxiranes under mild reaction conditions to afford β-hydroxyacetylenes in high yields.",

author = "Masahiko Yamaguchi and Ichiro Hirao",

year = "1983",

doi = "10.1016/S0040-4039(00)81416-1",

language = "English",

volume = "24",

pages = "391--394",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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number = "4",

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T1 - An efficient method for the alkynylation of oxiranes using alkynyl boranes

AU - Yamaguchi, Masahiko

AU - Hirao, Ichiro

PY - 1983

Y1 - 1983

N2 - Alkynyl boranes, generated in situ from lithium acetylides and boron trifluoride etherate, were found to react with oxiranes under mild reaction conditions to afford β-hydroxyacetylenes in high yields.

AB - Alkynyl boranes, generated in situ from lithium acetylides and boron trifluoride etherate, were found to react with oxiranes under mild reaction conditions to afford β-hydroxyacetylenes in high yields.

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U2 - 10.1016/S0040-4039(00)81416-1

DO - 10.1016/S0040-4039(00)81416-1

M3 - Article

AN - SCOPUS:0001641492

VL - 24

SP - 391

EP - 394

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 4

ER -

An efficient method for the alkynylation of oxiranes using alkynyl boranes

Abstract

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