An effective combination catalyst of CeO2and zeolite for the direct synthesis of diethyl carbonate from CO2and ethanol with 2,2-diethoxypropane as a dehydrating agent

Tao Chang; Masazumi Tamura; Yoshinao Nakagawa; Norihisa Fukaya; Jun Chul Choi; Takayoshi Mishima; Seiji Matsumoto; Satoshi Hamura; Keiichi Tomishige

doi:10.1039/d0gc02717k

An effective combination catalyst of CeO₂and zeolite for the direct synthesis of diethyl carbonate from CO₂and ethanol with 2,2-diethoxypropane as a dehydrating agent

Tao Chang, Masazumi Tamura, Yoshinao Nakagawa, Norihisa Fukaya, Jun Chul Choi, Takayoshi Mishima, Seiji Matsumoto, Satoshi Hamura, Keiichi Tomishige

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The combination catalyst of CeO2 and H-FAU zeolite was effective for the direct synthesis of diethyl carbonate from CO2 and ethanol with 2,2-diethoxypropane as a dehydrating regent, where H-FAU catalyzed hydrolysis of 2,2-diethoxypropane. The combination catalyst provided high activity and a high diethyl carbonate yield of 72% based on 2,2-diethoxypropane at a low temperature of 393 K. This journal is

Original language	English
Pages (from-to)	7321-7327
Number of pages	7
Journal	Green Chemistry
Volume	22
Issue number	21
DOIs	https://doi.org/10.1039/d0gc02717k
Publication status	Published - 2020 Nov 7
Externally published	Yes

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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An effective combination catalyst of CeO₂and zeolite for the direct synthesis of diethyl carbonate from CO₂and ethanol with 2,2-diethoxypropane as a dehydrating agent. / Chang, Tao; Tamura, Masazumi; Nakagawa, Yoshinao; Fukaya, Norihisa; Choi, Jun Chul; Mishima, Takayoshi; Matsumoto, Seiji; Hamura, Satoshi; Tomishige, Keiichi.

In: Green Chemistry, Vol. 22, No. 21, 07.11.2020, p. 7321-7327.

Research output: Contribution to journal › Article › peer-review

Chang, Tao ; Tamura, Masazumi ; Nakagawa, Yoshinao ; Fukaya, Norihisa ; Choi, Jun Chul ; Mishima, Takayoshi ; Matsumoto, Seiji ; Hamura, Satoshi ; Tomishige, Keiichi. / An effective combination catalyst of CeO₂and zeolite for the direct synthesis of diethyl carbonate from CO₂and ethanol with 2,2-diethoxypropane as a dehydrating agent. In: Green Chemistry. 2020 ; Vol. 22, No. 21. pp. 7321-7327.

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abstract = "The combination catalyst of CeO2 and H-FAU zeolite was effective for the direct synthesis of diethyl carbonate from CO2 and ethanol with 2,2-diethoxypropane as a dehydrating regent, where H-FAU catalyzed hydrolysis of 2,2-diethoxypropane. The combination catalyst provided high activity and a high diethyl carbonate yield of 72% based on 2,2-diethoxypropane at a low temperature of 393 K. This journal is ",

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AU - Chang, Tao

AU - Tamura, Masazumi

AU - Nakagawa, Yoshinao

AU - Fukaya, Norihisa

AU - Choi, Jun Chul

AU - Mishima, Takayoshi

AU - Matsumoto, Seiji

AU - Hamura, Satoshi

AU - Tomishige, Keiichi

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An effective combination catalyst of CeO₂and zeolite for the direct synthesis of diethyl carbonate from CO₂and ethanol with 2,2-diethoxypropane as a dehydrating agent

Abstract

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