An antiferromagnetically coupled heterometal Cu6Fe wheel

Ryo Saiki; Norifumi Yoshida; Norihisa Hoshino; Graham N. Newton; Takuya Shiga; Hiroki Oshio

doi:10.1246/cl.170365

An antiferromagnetically coupled heterometal Cu₆Fe wheel

Ryo Saiki, Norifumi Yoshida, Norihisa Hoshino, Graham N. Newton, Takuya Shiga, Hiroki Oshio

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A heterometal Cu₆Fe wheel molecule, [Cu^II₆Fe^III(HL)₆(OH)₂(OCH₃)₄](NO₃)₃·6H₂O (1·6H₂O) (H₂L = 1-(2-pyridine)-3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H₂L with copper and iron sources. X-ray structural analysis reveals that the heptanuclear wheel cluster consists of a central Fe(III) ion surrounded by six Cu(II) ions, linked through methoxo- and hydroxo-bridges. Cryomagnetic studies indicate intramolecular antiferromagnetic interactions were operative.

Original language	English
Pages (from-to)	1197-1199
Number of pages	3
Journal	Chemistry Letters
Volume	46
Issue number	8
DOIs	https://doi.org/10.1246/cl.170365
Publication status	Published - 2017

Keywords

Antiferromagnetic interaction
Heterometal polynuclear complex
Wheel complex

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.170365

Cite this

@article{b6cb8dd02e70400c87f0abb19465d245,

title = "An antiferromagnetically coupled heterometal Cu6Fe wheel",

abstract = "A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6(OH)2(OCH3)4](NO3)3·6H2O (1·6H2O) (H2L = 1-(2-pyridine)-3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals that the heptanuclear wheel cluster consists of a central Fe(III) ion surrounded by six Cu(II) ions, linked through methoxo- and hydroxo-bridges. Cryomagnetic studies indicate intramolecular antiferromagnetic interactions were operative.",

keywords = "Antiferromagnetic interaction, Heterometal polynuclear complex, Wheel complex",

author = "Ryo Saiki and Norifumi Yoshida and Norihisa Hoshino and Newton, {Graham N.} and Takuya Shiga and Hiroki Oshio",

note = "Funding Information: This work was supported by a JSPS KAKENHI Grant Number JP16H06523 (Coordination Asymmetry). Publisher Copyright: {\textcopyright} 2017 The Chemical Society of Japan.",

year = "2017",

doi = "10.1246/cl.170365",

language = "English",

volume = "46",

pages = "1197--1199",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "8",

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TY - JOUR

T1 - An antiferromagnetically coupled heterometal Cu6Fe wheel

AU - Saiki, Ryo

AU - Yoshida, Norifumi

AU - Hoshino, Norihisa

AU - Newton, Graham N.

AU - Shiga, Takuya

AU - Oshio, Hiroki

PY - 2017

Y1 - 2017

N2 - A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6(OH)2(OCH3)4](NO3)3·6H2O (1·6H2O) (H2L = 1-(2-pyridine)-3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals that the heptanuclear wheel cluster consists of a central Fe(III) ion surrounded by six Cu(II) ions, linked through methoxo- and hydroxo-bridges. Cryomagnetic studies indicate intramolecular antiferromagnetic interactions were operative.

AB - A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6(OH)2(OCH3)4](NO3)3·6H2O (1·6H2O) (H2L = 1-(2-pyridine)-3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals that the heptanuclear wheel cluster consists of a central Fe(III) ion surrounded by six Cu(II) ions, linked through methoxo- and hydroxo-bridges. Cryomagnetic studies indicate intramolecular antiferromagnetic interactions were operative.

KW - Antiferromagnetic interaction

KW - Heterometal polynuclear complex

KW - Wheel complex

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DO - 10.1246/cl.170365

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EP - 1199

JO - Chemistry Letters

JF - Chemistry Letters

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