Abstract
A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6(OH)2(OCH3)4](NO3)3·6H2O (1·6H2O) (H2L = 1-(2-pyridine)-3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals that the heptanuclear wheel cluster consists of a central Fe(III) ion surrounded by six Cu(II) ions, linked through methoxo- and hydroxo-bridges. Cryomagnetic studies indicate intramolecular antiferromagnetic interactions were operative.
Original language | English |
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Pages (from-to) | 1197-1199 |
Number of pages | 3 |
Journal | Chemistry Letters |
Volume | 46 |
Issue number | 8 |
DOIs | |
Publication status | Published - 2017 |
Externally published | Yes |
Keywords
- Antiferromagnetic interaction
- Heterometal polynuclear complex
- Wheel complex
ASJC Scopus subject areas
- Chemistry(all)