An activated catalyst RhH(PPh3)4-dppe-Me 2S2 for α-methylthiolaton of α-phenyl ketones

Mieko Arisawa, Fumihiko Toriyama, Masahiko Yamaguchi

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

In the presence of catalytic amounts of RhH(PPh3)4, 1,2-bis(diphenylphosphino)ethane (dppe), and dimethyl disulfide, cyclic and acyclic α-phenyl ketones reacted with p-cyano-α- methylthioacetophenone giving α-methylthio-α-phenylketones. The activated catalyst containing dimethyl disulfide was effective for the α-methylthiolation reaction of these less reactive substrates.

Original languageEnglish
Pages (from-to)18-23
Number of pages6
JournalHeteroatom Chemistry
Volume22
Issue number1
DOIs
Publication statusPublished - 2011

ASJC Scopus subject areas

  • Chemistry(all)

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