Ammonia adsorption on diffusion into thin ice films grown on Pt(111)

T. Takaoka, M. Inamura, S. Yanagimachi, I. Kusunoki, T. Komeda

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The study of ammonia adsorption on and diffusion into thin ice films grown on a Pt(111) surface using Fourier transform infrared spectroscopy (FTIR) and thermal desorption spectroscopy was presented. An intriguing feature at 1470 cm-1 in the FTIR spectra was detected after exposing the crystalline ice film to ammonia molecules at 45 K. A feature at 1260 cm-1, which appears after annealing the ammonia/ice film, was also detected. It was shown that the feature corresponds to the ammonia molecules which reach the ice/Pt(111) interface through the ice film.

Original languageEnglish
Pages (from-to)4331-4338
Number of pages8
JournalJournal of Chemical Physics
Volume121
Issue number9
DOIs
Publication statusPublished - 2004 Sep 1

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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