[Al12P13O52]3-[(CH2)6N4H3]3+: An anionic aluminophosphate molecular sieve with bronsted acidity

W. Yan, J. Yu, R. Xu, G. Zhu, F. Xiao, Y. Han, Kazumasa Sugiyama, O. Terasaki

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72 Citations (Scopus)


The first anionic aluminophosphate molecular sieve [Al12P13O52]3-[(CH2)6N4H3]3+, denoted AlPO-CJB1, which possesses Bronsted acidity upon removing the templates, is reported. The framework is constructed from strict alternation of Alcentered polyhedra (AlO4 and AlO5) and P-centered PO4 tetrahedra by sharing oxygen atoms at vertices, which creates the anionic open-framework in contrast to previous AlPO(4-n) with neutral open-frameworks.

Original languageEnglish
Pages (from-to)2517-2519
Number of pages3
JournalChemistry of Materials
Issue number9
Publication statusPublished - 2000 Oct 21

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

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