Allosteric silver(I) ion binding with peripheral π clefts of a ce(IV) double decker porphyrin

Masato Ikeda, Tomoyuki Tanida, Masayuki Takeuchi, Seiji Shinkai

Research output: Contribution to journalArticlepeer-review

67 Citations (Scopus)

Abstract

(Formula presented) A cerium(IV) double decker porphyrin (1) bearing four 4-methoxyphenyl groups was synthesized. Compound 1 shows a positive, homotoropic allosteric effect in metal recognition of Ag+ ion, and the peripheral π clefts of 1 act as effective binding sites for Ag+ ion.

Original languageEnglish
Pages (from-to)1803-1805
Number of pages3
JournalOrganic letters
Volume2
Issue number13
DOIs
Publication statusPublished - 2000 Jun 29
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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