Alignment of conjugated polymers by supramolecular porphyrin oligomer (2)

Rie Wakabayashi, Yohei Kubo, Masayuki Takeuchi, Seiji Shinkai, Kenji Kaneko

Research output: Contribution to conferencePaperpeer-review

Abstract

We proposed a novel approach for aligning and organizing of conjugated polymers by Aligners, which possess several binding sites for conjugated polymers. In this system, however, the supramolecular assemblies between Aligners and polymers are under thermodynamic control and could be destroyed by dilution or other external factors. Aligner 3, which possesses olefins as reaction sites, can bind a guest poly(phenylene-ethynylene) (poly-PPE) and organize assemblies of poly-PPEs. These assemblies were able to be immobilized by metathesis reaction.

Original languageEnglish
Pages4099
Number of pages1
Publication statusPublished - 2005
Externally publishedYes
Event54th SPSJ Symposium on Macromolecules - Yamagata, Japan
Duration: 2005 Sep 202005 Sep 22

Other

Other54th SPSJ Symposium on Macromolecules
CountryJapan
CityYamagata
Period05/9/2005/9/22

Keywords

  • Conjugated polymer
  • Metathesis reaction
  • Molecular recognition
  • Supramolecular chemistry

ASJC Scopus subject areas

  • Engineering(all)

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