Aldimine-directed branched-selective hydroarylation of styrenes

Pin Sheng Lee, Naohiko Yoshikai

Research output: Contribution to journalArticlepeer-review

91 Citations (Scopus)

Abstract

Branching out: A simple and inexpensive cobalt/triarylphosphine catalyst promotes aldimine-directed hydroarylation of styrene with high branched regioselectivity to afford 1,1-diarylethane derivatives in good yields under mild reaction conditions. The ortho-formyl group in the hydroarylation products is amenable to dehydrative cyclization, to give fused polycyclic aromatic hydrocarbons, as well as decarbonylative removal.

Original languageEnglish
Pages (from-to)1240-1244
Number of pages5
JournalAngewandte Chemie - International Edition
Volume52
Issue number4
DOIs
Publication statusPublished - 2013 Jan 21
Externally publishedYes

Keywords

  • alkenes
  • arenes
  • C-H activation
  • cobalt
  • synthetic methods

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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