Alcoholysis of benzotrichloride studied by liquid beam - Multiphoton ionization technique

Noriko Horimoto, Fumitaka Mafuné, Tamotsu Kondow

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Chemical reactions of benzotrichloride in an alcohol solution initiated by multiphoton ionization were observed by irradiation of a tightly focused laser beam at wavelength of 274 nm. The product ions ejected from the liquid surface were analyzed by a time-of-flight mass spectrometer. The mass spectra of the ions indicate that alcoholysis occurs between PhCCl+2 produced by multiphoton ionization and alcohol molecules, ROH, giving PhCCl(OR)+ and PhC(OR)+2.

Original languageEnglish
Pages (from-to)159-160
Number of pages2
JournalChemistry Letters
Issue number2
DOIs
Publication statusPublished - 1997 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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