Alcoholysis of benzotrichloride studied by liquid beam - Multiphoton ionization technique

Noriko Horimoto; Fumitaka Mafuné; Tamotsu Kondow

doi:10.1246/cl.1997.159

Alcoholysis of benzotrichloride studied by liquid beam - Multiphoton ionization technique

Noriko Horimoto, Fumitaka Mafuné, Tamotsu Kondow

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Chemical reactions of benzotrichloride in an alcohol solution initiated by multiphoton ionization were observed by irradiation of a tightly focused laser beam at wavelength of 274 nm. The product ions ejected from the liquid surface were analyzed by a time-of-flight mass spectrometer. The mass spectra of the ions indicate that alcoholysis occurs between PhCCl⁺₂ produced by multiphoton ionization and alcohol molecules, ROH, giving PhCCl(OR)⁺ and PhC(OR)⁺₂.

Original language	English
Pages (from-to)	159-160
Number of pages	2
Journal	Chemistry Letters
Issue number	2
DOIs	https://doi.org/10.1246/cl.1997.159
Publication status	Published - 1997 Jan 1

ASJC Scopus subject areas

Chemistry(all)

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title = "Alcoholysis of benzotrichloride studied by liquid beam - Multiphoton ionization technique",

abstract = "Chemical reactions of benzotrichloride in an alcohol solution initiated by multiphoton ionization were observed by irradiation of a tightly focused laser beam at wavelength of 274 nm. The product ions ejected from the liquid surface were analyzed by a time-of-flight mass spectrometer. The mass spectra of the ions indicate that alcoholysis occurs between PhCCl+2 produced by multiphoton ionization and alcohol molecules, ROH, giving PhCCl(OR)+ and PhC(OR)+2.",

author = "Noriko Horimoto and Fumitaka Mafun{\'e} and Tamotsu Kondow",

year = "1997",

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doi = "10.1246/cl.1997.159",

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AU - Horimoto, Noriko

AU - Mafuné, Fumitaka

AU - Kondow, Tamotsu

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Y1 - 1997/1/1

N2 - Chemical reactions of benzotrichloride in an alcohol solution initiated by multiphoton ionization were observed by irradiation of a tightly focused laser beam at wavelength of 274 nm. The product ions ejected from the liquid surface were analyzed by a time-of-flight mass spectrometer. The mass spectra of the ions indicate that alcoholysis occurs between PhCCl+2 produced by multiphoton ionization and alcohol molecules, ROH, giving PhCCl(OR)+ and PhC(OR)+2.

AB - Chemical reactions of benzotrichloride in an alcohol solution initiated by multiphoton ionization were observed by irradiation of a tightly focused laser beam at wavelength of 274 nm. The product ions ejected from the liquid surface were analyzed by a time-of-flight mass spectrometer. The mass spectra of the ions indicate that alcoholysis occurs between PhCCl+2 produced by multiphoton ionization and alcohol molecules, ROH, giving PhCCl(OR)+ and PhC(OR)+2.

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JF - Chemistry Letters

SN - 0366-7022

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ER -

Alcoholysis of benzotrichloride studied by liquid beam - Multiphoton ionization technique

Abstract

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