AFM and XPS studies of a homoepitaxial diamond (001) surface nitrided using 500-eV N2+ ion beam

I. Kusunoki, Y. Igari, S. Ishidzuka, T. Takami, Tsuyoshi Takaoka, M. Nishitani-Gamo, T. Ando

Research output: Contribution to journalArticle

Abstract

A homoepitaxially grown p-type diamond (001) surface was nitrided by irradiation with a 500-eV N2+ ion beam. X-Ray photoelectron spectra (XPS) were taken in situ during the nitridation. The C1s and N1s XPS spectra were divided into three (A, ~ 284.7; B, ~ 285.6; and C, ~ 287.3 eV) and four (D, ~ 398.4; E, ~ 399.5; F, ~ 401.0; and G, ~ 1403.3 eV) components, respectively. The A component of the C1s core level originated from the diamond substrate lying under the nitrogen penetration zone. The B and C components came from the nitrogen-diluted layer and from the carbon nitrides, respectively. The composition ratio of nitrogen/carbon in the C phase, ND+F/CC, was 0.71. The Nall/CB+C ratio was 0.25. The morphology of the surface was also measured in air by atomic force microscope (AFM). It was found that grain-like material covered the surface after nitridation. A typical grain size was approximately 50 nm in diameter with a height of 5 nm. However, the grains themselves were not carbon nitrides. The crystallinity of the nitride was investigated using reflection high-energy electron diffraction (RHEED), but the formation of β-C3N4 could not be confirmed from the RHEED patterns, due to overlapping with the twin structures of diamond.

Original languageEnglish
Pages (from-to)1676-1680
Number of pages5
JournalDiamond and Related Materials
Volume10
Issue number9-10
DOIs
Publication statusPublished - 2001 Sep 1

Keywords

  • Carbon nitride
  • Diamond
  • Nitridation
  • X-Ray photoelectron spectroscopy (XPS)

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Chemistry(all)
  • Mechanical Engineering
  • Physics and Astronomy(all)
  • Materials Chemistry
  • Electrical and Electronic Engineering

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