Adsorption structure of 1,3-butadiene on Pd(1 1 0)

Satoshi Katano; Shigeru Ichihara; Hirohito Ogasawara; Hiroyuki S. Kato; Tadahiro Komeda; Maki Kawai; Kazunari Domen

doi:10.1016/S0039-6028(01)01928-8

Adsorption structure of 1,3-butadiene on Pd(1 1 0)

Satoshi Katano, Shigeru Ichihara, Hirohito Ogasawara, Hiroyuki S. Kato, Tadahiro Komeda, Maki Kawai, Kazunari Domen

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Adsorption structure of 1,3-butadiene chemisorbed on Pd(110) has been studied by high resolution electron energy loss spectroscopy (HREELS), near edge X-ray absorption fine structure (NEXAFS), and scanning tunneling microscopy (STM). The HREELS and NEXAFS results revealed that 1,3-butadiene is adsorbed with π-bond and the molecular plane is parallel to the surface, in which the C-C single bond in 1,3-butadiene on Pd(1 1 0) is aligned toward [1 1̄ 0]. The adsorption site and geometry were determined on the basis of the STM image analysis.

Original language	English
Pages (from-to)	164-168
Number of pages	5
Journal	Surface Science
Volume	502-503
DOIs	https://doi.org/10.1016/S0039-6028(01)01928-8
Publication status	Published - 2002 Apr 10
Externally published	Yes

Keywords

Adsorption kinetics
Chemisorption
Electron energy loss spectroscopy (EELS)
Near edge extended X-ray absorption fine structure (NEXAFS)
Palladium
Scanning tunneling microscopy

ASJC Scopus subject areas

Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films
Materials Chemistry

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title = "Adsorption structure of 1,3-butadiene on Pd(1 1 0)",

abstract = "Adsorption structure of 1,3-butadiene chemisorbed on Pd(110) has been studied by high resolution electron energy loss spectroscopy (HREELS), near edge X-ray absorption fine structure (NEXAFS), and scanning tunneling microscopy (STM). The HREELS and NEXAFS results revealed that 1,3-butadiene is adsorbed with π-bond and the molecular plane is parallel to the surface, in which the C-C single bond in 1,3-butadiene on Pd(1 1 0) is aligned toward [1 {\=1} 0]. The adsorption site and geometry were determined on the basis of the STM image analysis.",

keywords = "Adsorption kinetics, Chemisorption, Electron energy loss spectroscopy (EELS), Near edge extended X-ray absorption fine structure (NEXAFS), Palladium, Scanning tunneling microscopy",

author = "Satoshi Katano and Shigeru Ichihara and Hirohito Ogasawara and Kato, {Hiroyuki S.} and Tadahiro Komeda and Maki Kawai and Kazunari Domen",

year = "2002",

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doi = "10.1016/S0039-6028(01)01928-8",

language = "English",

volume = "502-503",

pages = "164--168",

journal = "Surface Science",

issn = "0039-6028",

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TY - JOUR

T1 - Adsorption structure of 1,3-butadiene on Pd(1 1 0)

AU - Katano, Satoshi

AU - Ichihara, Shigeru

AU - Ogasawara, Hirohito

AU - Kato, Hiroyuki S.

AU - Komeda, Tadahiro

AU - Kawai, Maki

AU - Domen, Kazunari

PY - 2002/4/10

Y1 - 2002/4/10

N2 - Adsorption structure of 1,3-butadiene chemisorbed on Pd(110) has been studied by high resolution electron energy loss spectroscopy (HREELS), near edge X-ray absorption fine structure (NEXAFS), and scanning tunneling microscopy (STM). The HREELS and NEXAFS results revealed that 1,3-butadiene is adsorbed with π-bond and the molecular plane is parallel to the surface, in which the C-C single bond in 1,3-butadiene on Pd(1 1 0) is aligned toward [1 1̄ 0]. The adsorption site and geometry were determined on the basis of the STM image analysis.

AB - Adsorption structure of 1,3-butadiene chemisorbed on Pd(110) has been studied by high resolution electron energy loss spectroscopy (HREELS), near edge X-ray absorption fine structure (NEXAFS), and scanning tunneling microscopy (STM). The HREELS and NEXAFS results revealed that 1,3-butadiene is adsorbed with π-bond and the molecular plane is parallel to the surface, in which the C-C single bond in 1,3-butadiene on Pd(1 1 0) is aligned toward [1 1̄ 0]. The adsorption site and geometry were determined on the basis of the STM image analysis.

KW - Adsorption kinetics

KW - Chemisorption

KW - Electron energy loss spectroscopy (EELS)

KW - Near edge extended X-ray absorption fine structure (NEXAFS)

KW - Palladium

KW - Scanning tunneling microscopy

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U2 - 10.1016/S0039-6028(01)01928-8

DO - 10.1016/S0039-6028(01)01928-8

M3 - Article

AN - SCOPUS:0037051881

VL - 502-503

SP - 164

EP - 168

JO - Surface Science

JF - Surface Science

SN - 0039-6028

ER -

Adsorption structure of 1,3-butadiene on Pd(1 1 0)

Abstract

Keywords

ASJC Scopus subject areas

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