Adsorption structure of 1,3-butadiene on Pd(1 1 0)

Satoshi Katano, Shigeru Ichihara, Hirohito Ogasawara, Hiroyuki S. Kato, Tadahiro Komeda, Maki Kawai, Kazunari Domen

Research output: Contribution to journalArticlepeer-review

26 Citations (Scopus)

Abstract

Adsorption structure of 1,3-butadiene chemisorbed on Pd(110) has been studied by high resolution electron energy loss spectroscopy (HREELS), near edge X-ray absorption fine structure (NEXAFS), and scanning tunneling microscopy (STM). The HREELS and NEXAFS results revealed that 1,3-butadiene is adsorbed with π-bond and the molecular plane is parallel to the surface, in which the C-C single bond in 1,3-butadiene on Pd(1 1 0) is aligned toward [1 1̄ 0]. The adsorption site and geometry were determined on the basis of the STM image analysis.

Original languageEnglish
Pages (from-to)164-168
Number of pages5
JournalSurface Science
Volume502-503
DOIs
Publication statusPublished - 2002 Apr 10
Externally publishedYes

Keywords

  • Adsorption kinetics
  • Chemisorption
  • Electron energy loss spectroscopy (EELS)
  • Near edge extended X-ray absorption fine structure (NEXAFS)
  • Palladium
  • Scanning tunneling microscopy

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Adsorption structure of 1,3-butadiene on Pd(1 1 0)'. Together they form a unique fingerprint.

Cite this