Adsorption and catalytic properties of the inner nanospace of a gigantic ring-shaped polyoxometalate cluster

Shin Ichiro Noro; Ryo Tsunashima; Yuichi Kamiya; Kazuhiro Uemura; Hidetoshi Kita; Leroy Cronin; Tomoyuki Akutagawa; Takayoshi Nakamura

doi:10.1002/anie.200903142

Adsorption and catalytic properties of the inner nanospace of a gigantic ring-shaped polyoxometalate cluster

Shin Ichiro Noro, Ryo Tsunashima, Yuichi Kamiya, Kazuhiro Uemura, Hidetoshi Kita, Leroy Cronin, Tomoyuki Akutagawa, Takayoshi Nakamura

Research output: Contribution to journal › Article › peer-review

77 Citations (Scopus)

Abstract

Functional inner space: A gigantic ringshaped {Mo154} polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water-tolerant solid acid catalyst (see scheme).

Original language	English
Pages (from-to)	8703-8706
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	46
DOIs	https://doi.org/10.1002/anie.200903142
Publication status	Published - 2009 Nov 2
Externally published	Yes

Keywords

Adsorption
Heterogeneous catalysis
Microporous materials
Organic-inorganic hybrid composites
Polyoxometalates

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200903142

Cite this

@article{f50dc81193664e03ae1c93a527b8d1a3,

title = "Adsorption and catalytic properties of the inner nanospace of a gigantic ring-shaped polyoxometalate cluster",

abstract = "Functional inner space: A gigantic ringshaped {Mo154} polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water-tolerant solid acid catalyst (see scheme).",

keywords = "Adsorption, Heterogeneous catalysis, Microporous materials, Organic-inorganic hybrid composites, Polyoxometalates",

author = "Noro, {Shin Ichiro} and Ryo Tsunashima and Yuichi Kamiya and Kazuhiro Uemura and Hidetoshi Kita and Leroy Cronin and Tomoyuki Akutagawa and Takayoshi Nakamura",

year = "2009",

month = nov,

day = "2",

doi = "10.1002/anie.200903142",

language = "English",

volume = "48",

pages = "8703--8706",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "46",

}

TY - JOUR

T1 - Adsorption and catalytic properties of the inner nanospace of a gigantic ring-shaped polyoxometalate cluster

AU - Noro, Shin Ichiro

AU - Tsunashima, Ryo

AU - Kamiya, Yuichi

AU - Uemura, Kazuhiro

AU - Kita, Hidetoshi

AU - Cronin, Leroy

AU - Akutagawa, Tomoyuki

AU - Nakamura, Takayoshi

PY - 2009/11/2

Y1 - 2009/11/2

N2 - Functional inner space: A gigantic ringshaped {Mo154} polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water-tolerant solid acid catalyst (see scheme).

AB - Functional inner space: A gigantic ringshaped {Mo154} polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water-tolerant solid acid catalyst (see scheme).

KW - Adsorption

KW - Heterogeneous catalysis

KW - Microporous materials

KW - Organic-inorganic hybrid composites

KW - Polyoxometalates

UR - http://www.scopus.com/inward/record.url?scp=70350576436&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=70350576436&partnerID=8YFLogxK

U2 - 10.1002/anie.200903142

DO - 10.1002/anie.200903142

M3 - Article

C2 - 19824029

AN - SCOPUS:70350576436

SN - 1433-7851

VL - 48

SP - 8703

EP - 8706

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 46

ER -

Adsorption and catalytic properties of the inner nanospace of a gigantic ring-shaped polyoxometalate cluster

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this