Adsorption and catalytic properties of the inner nanospace of a gigantic ring-shaped polyoxometalate cluster

Shin Ichiro Noro, Ryo Tsunashima, Yuichi Kamiya, Kazuhiro Uemura, Hidetoshi Kita, Leroy Cronin, Tomoyuki Akutagawa, Takayoshi Nakamura

Research output: Contribution to journalArticlepeer-review

64 Citations (Scopus)

Abstract

Functional inner space: A gigantic ringshaped {Mo154} polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water-tolerant solid acid catalyst (see scheme).

Original languageEnglish
Pages (from-to)8703-8706
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number46
DOIs
Publication statusPublished - 2009 Nov 2
Externally publishedYes

Keywords

  • Adsorption
  • Heterogeneous catalysis
  • Microporous materials
  • Organic-inorganic hybrid composites
  • Polyoxometalates

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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