Addition of HCl to a base-stabilized hydrido(silylene)tungsten complex and reactivity of the adduct toward LiAlH4

Hiroyuki Sakaba, Takeshi Hirata, Chizuko Kabuto, Hiroshi Horino

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

The reaction of cis-Cp*(CO)2HW=SiPh2·Py (1, Py = pyridine) with HCl gave an adduct Cp*(CO)2H2WSiPh2Cl (2). Treatment of 2 with excess LiAlH4 afforded an anionic complex Li[cis-Cp*(CO)2HWSiHPh2] (4), and the same product was obtained by the reaction of 1 with LiAlH4.

Original languageEnglish
Pages (from-to)1078-1079
Number of pages2
JournalChemistry Letters
Issue number11
DOIs
Publication statusPublished - 2001 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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