Ab initio study of excitation energy transfer between quantum dots and dye molecules

Hiroyuki Tamura, Jean Maurice Mallet, Martin Oheim, Irene Burghardt

    Research output: Contribution to journalArticlepeer-review

    23 Citations (Scopus)

    Abstract

    We investigate excitation energy transfer between a semiconductor nanocrystal (NC) and an organic dye molecule, using ab initio calculations. The electronic coupling is evaluated based on the full Coulombic interaction between the NC and dye transition densities. We explore the effect of the NC-dye relative configurations on the electronic coupling, using a (CdSe)6 cluster and a rhodamine cation as a simplified model system. Our analysis demonstrates the limitations of the commonly used Förster theory for the NC-dye system and highlights the importance of considering the full Coulombic interactions of donor and acceptor. We find that energy transfer involves several electronic states and can occur even from optically dark states of the NC. The consequences for larger NC-dye systems are discussed.

    Original languageEnglish
    Pages (from-to)7548-7552
    Number of pages5
    JournalJournal of Physical Chemistry C
    Volume113
    Issue number18
    DOIs
    Publication statusPublished - 2009 May 7

    ASJC Scopus subject areas

    • Electronic, Optical and Magnetic Materials
    • Energy(all)
    • Physical and Theoretical Chemistry
    • Surfaces, Coatings and Films

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