A unique diruthenium(II, III) unit surrounded by tridentate ligands of N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate

Hitoshi Miyasaka, Ken Ichi Sugiura, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

A new metal-metal bonded diruthenium(II, III) compound with a dianionic tridentate ligand, N-(2-pyridyl)-2-oxy-5-chloro-benzylaminate (5-Clsalpy2-), was synthesized and structurally characterized as Li2(THF)4Cl[Ru2(5-Clsalpy)3] (1). The 5-Clsalpy2- ligand that acts as a bridging/chelating co-ligand afforded a unique coordination mode of [M-M bridging/equatorial-chelating] in addition to the "common" mode of [M-M bridging/axial-chelating] around the diruthenium unit of 1.

Original languageEnglish
Pages (from-to)1078-1080
Number of pages3
JournalInorganic Chemistry Communications
Volume6
Issue number8
DOIs
Publication statusPublished - 2003 Aug 1
Externally publishedYes

Keywords

  • Crystal structure
  • Metal-metal bond
  • Ruthenium complex
  • Tridentate ligand

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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