A unique diruthenium(II, III) unit surrounded by tridentate ligands of N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate

Hitoshi Miyasaka; Ken Ichi Sugiura; Masahiro Yamashita

doi:10.1016/S1387-7003(03)00185-0

A unique diruthenium(II, III) unit surrounded by tridentate ligands of N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate

Hitoshi Miyasaka, Ken Ichi Sugiura, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A new metal-metal bonded diruthenium(II, III) compound with a dianionic tridentate ligand, N-(2-pyridyl)-2-oxy-5-chloro-benzylaminate (5-Clsalpy^2-), was synthesized and structurally characterized as Li₂(THF)₄Cl[Ru₂(5-Clsalpy)₃] (1). The 5-Clsalpy^2- ligand that acts as a bridging/chelating co-ligand afforded a unique coordination mode of [M-M bridging/equatorial-chelating] in addition to the "common" mode of [M-M bridging/axial-chelating] around the diruthenium unit of 1.

Original language	English
Pages (from-to)	1078-1080
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	8
DOIs	https://doi.org/10.1016/S1387-7003(03)00185-0
Publication status	Published - 2003 Aug 1
Externally published	Yes

Keywords

Crystal structure
Metal-metal bond
Ruthenium complex
Tridentate ligand

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "A unique diruthenium(II, III) unit surrounded by tridentate ligands of N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate",

abstract = "A new metal-metal bonded diruthenium(II, III) compound with a dianionic tridentate ligand, N-(2-pyridyl)-2-oxy-5-chloro-benzylaminate (5-Clsalpy2-), was synthesized and structurally characterized as Li2(THF)4Cl[Ru2(5-Clsalpy)3] (1). The 5-Clsalpy2- ligand that acts as a bridging/chelating co-ligand afforded a unique coordination mode of [M-M bridging/equatorial-chelating] in addition to the {"}common{"} mode of [M-M bridging/axial-chelating] around the diruthenium unit of 1.",

keywords = "Crystal structure, Metal-metal bond, Ruthenium complex, Tridentate ligand",

author = "Hitoshi Miyasaka and Sugiura, {Ken Ichi} and Masahiro Yamashita",

year = "2003",

month = aug,

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doi = "10.1016/S1387-7003(03)00185-0",

language = "English",

volume = "6",

pages = "1078--1080",

journal = "Inorganic Chemistry Communication",

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publisher = "Elsevier BV",

number = "8",

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T1 - A unique diruthenium(II, III) unit surrounded by tridentate ligands of N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate

AU - Miyasaka, Hitoshi

AU - Sugiura, Ken Ichi

AU - Yamashita, Masahiro

PY - 2003/8/1

Y1 - 2003/8/1

N2 - A new metal-metal bonded diruthenium(II, III) compound with a dianionic tridentate ligand, N-(2-pyridyl)-2-oxy-5-chloro-benzylaminate (5-Clsalpy2-), was synthesized and structurally characterized as Li2(THF)4Cl[Ru2(5-Clsalpy)3] (1). The 5-Clsalpy2- ligand that acts as a bridging/chelating co-ligand afforded a unique coordination mode of [M-M bridging/equatorial-chelating] in addition to the "common" mode of [M-M bridging/axial-chelating] around the diruthenium unit of 1.

AB - A new metal-metal bonded diruthenium(II, III) compound with a dianionic tridentate ligand, N-(2-pyridyl)-2-oxy-5-chloro-benzylaminate (5-Clsalpy2-), was synthesized and structurally characterized as Li2(THF)4Cl[Ru2(5-Clsalpy)3] (1). The 5-Clsalpy2- ligand that acts as a bridging/chelating co-ligand afforded a unique coordination mode of [M-M bridging/equatorial-chelating] in addition to the "common" mode of [M-M bridging/axial-chelating] around the diruthenium unit of 1.

KW - Crystal structure

KW - Metal-metal bond

KW - Ruthenium complex

KW - Tridentate ligand

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DO - 10.1016/S1387-7003(03)00185-0

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SP - 1078

EP - 1080

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

IS - 8

ER -

A unique diruthenium(II, III) unit surrounded by tridentate ligands of N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate

Abstract

Keywords

ASJC Scopus subject areas

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