A three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations

Hitoshi Miyasaka; Takaumi Morita; Masahiro Yamashita

doi:10.1039/c0cc02031a

A three-dimensional network of two-electron-transferred [Ru₂]₂TCNQ exhibiting anomalous conductance due to charge fluctuations

Hitoshi Miyasaka, Takaumi Morita, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

A new D₂A-type charge-transfer three-dimensional network with a charge distribution of [(Ru₂)^ε+-(BTDA-TCNQ^2ε−)-(Ru₂)^ε+] where ε’ 1, which exhibits a sudden decrease in electronic resistance, formed from the assembly of a paddlewheel diruthenium(ii, ii) complex ([Ru₂]) as a donor (D) and bis(1,2,5-thiadiazolo)tetracyanoquinodimethane (BTDA-TCNQ) as an acceptor (A).

Original language	English
Pages (from-to)	271-273
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	1
DOIs	https://doi.org/10.1039/c0cc02031a
Publication status	Published - 2011 Dec 6

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A new D2A-type charge-transfer three-dimensional network with a charge distribution of [(Ru2)ε+-(BTDA-TCNQ2ε−)-(Ru2)ε+] where ε{\textquoteright} 1, which exhibits a sudden decrease in electronic resistance, formed from the assembly of a paddlewheel diruthenium(ii, ii) complex ([Ru2]) as a donor (D) and bis(1,2,5-thiadiazolo)tetracyanoquinodimethane (BTDA-TCNQ) as an acceptor (A).",

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