A three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations

Hitoshi Miyasaka, Takaumi Morita, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

49 Citations (Scopus)

Abstract

A new D2A-type charge-transfer three-dimensional network with a charge distribution of [(Ru2)ε+-(BTDA-TCNQ2ε−)-(Ru2)ε+] where ε’ 1, which exhibits a sudden decrease in electronic resistance, formed from the assembly of a paddlewheel diruthenium(ii, ii) complex ([Ru2]) as a donor (D) and bis(1,2,5-thiadiazolo)tetracyanoquinodimethane (BTDA-TCNQ) as an acceptor (A).

Original languageEnglish
Pages (from-to)271-273
Number of pages3
JournalChemical Communications
Volume47
Issue number1
DOIs
Publication statusPublished - 2011 Dec 6

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'A three-dimensional network of two-electron-transferred [Ru<sub>2</sub>]<sub>2</sub>TCNQ exhibiting anomalous conductance due to charge fluctuations'. Together they form a unique fingerprint.

Cite this