A thermodynamic study of the phase equilibria in the Bi-Sn-Sb system

H. Ohtani; K. Ishida

doi:10.1007/BF02651369

A thermodynamic study of the phase equilibria in the Bi-Sn-Sb system

H. Ohtani, K. Ishida

Division of Inorganic Material Research

Research output: Contribution to journal › Article › peer-review

106 Citations (Scopus)

Abstract

A thermodynamic study has been carried out on the Bi-Sn-Sb ternary alloy system. The Gibbs energy of individual phases has been approximated using the regular solution, two-sublattice model, and the thermodynamic parameters for each phase have been evaluated using the available experimental information on phase boundaries and other related thermodynamic properties. Thermal analysis experiments have also been performed on several ternary alloys to re-examine and augment the available ternary experimental data. The set of evaluated thermodynamic parameters arrived at in this study, enables reproducible calculations of the liquidus and solidus temperatures and vertical section diagrams quite satisfactorily.

Original language	English
Pages (from-to)	747-755
Number of pages	9
Journal	Journal of Electronic Materials
Volume	23
Issue number	8
DOIs	https://doi.org/10.1007/BF02651369
Publication status	Published - 1994 Aug 1

Keywords

Bi-Sn-Sb
phase diagram
solder materials

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering
Materials Chemistry

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10.1007/BF02651369

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N2 - A thermodynamic study has been carried out on the Bi-Sn-Sb ternary alloy system. The Gibbs energy of individual phases has been approximated using the regular solution, two-sublattice model, and the thermodynamic parameters for each phase have been evaluated using the available experimental information on phase boundaries and other related thermodynamic properties. Thermal analysis experiments have also been performed on several ternary alloys to re-examine and augment the available ternary experimental data. The set of evaluated thermodynamic parameters arrived at in this study, enables reproducible calculations of the liquidus and solidus temperatures and vertical section diagrams quite satisfactorily.

AB - A thermodynamic study has been carried out on the Bi-Sn-Sb ternary alloy system. The Gibbs energy of individual phases has been approximated using the regular solution, two-sublattice model, and the thermodynamic parameters for each phase have been evaluated using the available experimental information on phase boundaries and other related thermodynamic properties. Thermal analysis experiments have also been performed on several ternary alloys to re-examine and augment the available ternary experimental data. The set of evaluated thermodynamic parameters arrived at in this study, enables reproducible calculations of the liquidus and solidus temperatures and vertical section diagrams quite satisfactorily.

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KW - solder materials

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A thermodynamic study of the phase equilibria in the Bi-Sn-Sb system

Abstract

Keywords

ASJC Scopus subject areas

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