A theoretical study of resonance Raman scattering from molecules. IV. Anharmonic effect

H. Kono, Z. Z. Ho, S. H. Lin

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

We have investigated the effects of anharmonicity on the resonance Raman scattering by using the Morse potential for molecular vibration. The Raman intensity is computed by the conventional sum-over-states method. Several conditions in which the anharmonicity effects are manifest have been derived from our numerical calculations. We have also compared our exact results with those of the short time approximation, which is the most tractable approximation in the time-dependent theory of Raman scattering proposed by Heller et al.

Original languageEnglish
Pages (from-to)1760-1765
Number of pages6
JournalThe Journal of Chemical Physics
Volume80
Issue number5
DOIs
Publication statusPublished - 1983

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'A theoretical study of resonance Raman scattering from molecules. IV. Anharmonic effect'. Together they form a unique fingerprint.

Cite this