A supramolecular cation in an electrically conducting nickel dithiolate salt

Tomoyuki Akutagawa, Takayoshi Nakamura, Tamotsu Inabe, Allan E. Underhill

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

A novel dimeric penta-coordinated ion cavity of [Li+]2[12-crown-4-ether]3 has been formed in the highly conducting Ni(dmit)2 salt. This salt showed a room-temperature conductivity of 30 S cm-1 and exhibited a semiconductor-semiconductor phase transition on the application of pressure or on lowering the temperature.

Original languageEnglish
Pages (from-to)183-185
Number of pages3
JournalJournal of Materials Chemistry
Volume7
Issue number2
DOIs
Publication statusPublished - 1997 Feb
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

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