A sulfate-bridged Cu II complex with 1-D helical-chain structure: Synthesis, structure and magnetic property

Li Juan Yang, Tao Lei, Wei Liu, Wen Qian Chen, Miao Shui Lin, Lei Li, Wu Li, Yahong Li

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

A new 1-D helical chain complex [Cu(H 2L)(SO 4)] ·CH 3OH (1) (H 2L = N,N-bis(3,5-dimethyl-2- hydroxybenzyl)-N-(2-pyridylmethyl)amine) was synthesized from the reaction of the tripodal tetradentate ligand H 2L with CuSO 4· 5H 2O under solvothermal conditions. Complex 1 was fully characterized by X-ray single crystal diffraction, elemental analysis and IR spectroscopy. X-ray analysis revealed that complex 1 displays a 1-D helical chain structure with the two adjacent metals being bridged by a sulfate ion. Each Cu II ion is penta-coordinated and exhibits a pseudo square pyramidal geometry. The low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed the ferromagnetic Cu IICu II interactions.

Original languageEnglish
Pages (from-to)12-15
Number of pages4
JournalInorganic Chemistry Communications
Volume21
DOIs
Publication statusPublished - 2012 Jul

Keywords

  • 1-D helical chain
  • Copper(II) complex
  • Magnetic property
  • Solvothermal synthesis

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'A sulfate-bridged Cu <sup>II</sup> complex with 1-D helical-chain structure: Synthesis, structure and magnetic property'. Together they form a unique fingerprint.

Cite this