A stable bicyclic compound with two Si = Si double bonds

T. Iwamoto, M. Tamura, C. Kabuto, M. Kira

Research output: Contribution to journalArticlepeer-review

72 Citations (Scopus)

Abstract

In contrast to carbon, silicon does not readily form double bonds, and compounds containing silicon-silicon double bonds can usually be stabilized only by protection with bulky substituents. We have isolated a silicon analog of spiropentadiene 1, a carbon double-ring compound that has not been isolated to date. In the crystal structure of tetrakis[tri(t-butyldimethylsilyl)silyl]spiropentasiladiene 2, a substantial deviation from the perpendicular arrangement of the two rings is observed, and the silicon-silicon double bonds are shown to be distorted. Spectroscopic data indicate pronounced interaction between two remote silicon-silicon double bonds in the molecule. Silicon-silicon bonds may be more accessible to synthesis than previously assumed.

Original languageEnglish
Pages (from-to)504-506
Number of pages3
JournalScience
Volume290
Issue number5491
DOIs
Publication statusPublished - 2000 Nov 13

ASJC Scopus subject areas

  • General

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