A stable 1,2-disilacyclohexene and its 14-electron palladium(0) complex

Takashi Abe, Takeaki Iwamoto, Mitsuo Kira

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

A novel stable cyclic disilene, 1,2-diphenyl-3,3,6,6- tetrakis(trimethylsilyl)-1,2-disilacyclohexene (1), was synthesized via the reaction of the corresponding 1,4-dilithiobutane with phenylchlorosilane. This new strategy would be applicable to the synthesis of stable cyclic disilenes having rather small residual substituents on unsaturated silicon atoms. A stable tricoordinate Y-shaped disilene palladium complex, 2, that was synthesized by the reaction of 1 with bis(tricyclohexylphosphine)palladium was found to have the strongest ?-complex character among known disilene palladium complexes.

Original languageEnglish
Pages (from-to)5008-5009
Number of pages2
JournalJournal of the American Chemical Society
Volume132
Issue number14
DOIs
Publication statusPublished - 2010 Apr 14

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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