A self-assembled, π-stacked complex as a finely-tunable magnetic aligner for biomolecular NMR applications

Sota Sato, Ryosuke Takeuchi, Maho Yagi-Utsumi, Takumi Yamaguchi, Yoshiki Yamaguchi, Koichi Kato, Makoto Fujita

    Research output: Contribution to journalArticle

    5 Citations (Scopus)

    Abstract

    The number of molecules constituting 1D intermolecular aggregates of the π-stacked self-assembled complex was controlled by altering the concentration and temperature. Enhanced magnetic orientation was observed for the aggregates with larger aggregation numbers. It was demonstrated that the designable complex aggregates serve as magnetic aligners to induce magnetic alignment upon an analyte protein coexisting in the solution, resulting in the observation of residual dipolar coupling (RDC) of the analyte. This journal is

    Original languageEnglish
    Pages (from-to)2540-2543
    Number of pages4
    JournalChemical Communications
    Volume51
    Issue number13
    DOIs
    Publication statusPublished - 2015 Feb 14

    ASJC Scopus subject areas

    • Catalysis
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Chemistry(all)
    • Surfaces, Coatings and Films
    • Metals and Alloys
    • Materials Chemistry

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  • Cite this

    Sato, S., Takeuchi, R., Yagi-Utsumi, M., Yamaguchi, T., Yamaguchi, Y., Kato, K., & Fujita, M. (2015). A self-assembled, π-stacked complex as a finely-tunable magnetic aligner for biomolecular NMR applications. Chemical Communications, 51(13), 2540-2543. https://doi.org/10.1039/c4cc09354b