A self-assembled, π-stacked complex as a finely-tunable magnetic aligner for biomolecular NMR applications

Sota Sato; Ryosuke Takeuchi; Maho Yagi-Utsumi; Takumi Yamaguchi; Yoshiki Yamaguchi; Koichi Kato; Makoto Fujita

doi:10.1039/c4cc09354b

A self-assembled, π-stacked complex as a finely-tunable magnetic aligner for biomolecular NMR applications

Sota Sato, Ryosuke Takeuchi, Maho Yagi-Utsumi, Takumi Yamaguchi, Yoshiki Yamaguchi, Koichi Kato, Makoto Fujita

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

The number of molecules constituting 1D intermolecular aggregates of the π-stacked self-assembled complex was controlled by altering the concentration and temperature. Enhanced magnetic orientation was observed for the aggregates with larger aggregation numbers. It was demonstrated that the designable complex aggregates serve as magnetic aligners to induce magnetic alignment upon an analyte protein coexisting in the solution, resulting in the observation of residual dipolar coupling (RDC) of the analyte. This journal is

Original language	English
Pages (from-to)	2540-2543
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	13
DOIs	https://doi.org/10.1039/c4cc09354b
Publication status	Published - 2015 Feb 14

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Sato, S., Takeuchi, R., Yagi-Utsumi, M., Yamaguchi, T., Yamaguchi, Y., Kato, K., & Fujita, M. (2015). A self-assembled, π-stacked complex as a finely-tunable magnetic aligner for biomolecular NMR applications. Chemical Communications, 51(13), 2540-2543. https://doi.org/10.1039/c4cc09354b

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