A scandium carbide endohedral metallofullerene: (Sc2C2)@C84

Chun Ru Wang; Tsutomu Kai; Testuo Tomiyama; Takuya Yoshida; Yuji Kobayashi; Eiji Nishibori; Masaki Takata; Makoto Sakata; Hisanori Shinohara

doi:10.1002/1521-3773(20010119)40:2<397::AID-ANIE397>3.0.CO;2-3

A scandium carbide endohedral metallofullerene: (Sc₂C₂)@C₈₄

Chun Ru Wang, Tsutomu Kai, Testuo Tomiyama, Takuya Yoshida, Yuji Kobayashi, Eiji Nishibori, Masaki Takata, Makoto Sakata, Hisanori Shinohara

Research output: Contribution to journal › Article › peer-review

277 Citations (Scopus)

Abstract

Not Sc₂@C₈₆ but Sc₂C₂@C₈₄: that is the conclusion of ¹³C NMR spectroscopic and synchrotron X-ray powder diffraction studies on a new metallofullerene obtained by arc discharge of Sc₂O₃/graphite rods. The picture shows a schematic representation of the deduced structure, in which the novel scandium carbide cluster Sc₂C₂ is encaged in D_2d-C₈₄.

Original language	English
Pages (from-to)	397-399
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	2
DOIs	https://doi.org/10.1002/1521-3773(20010119)40:2<397::AID-ANIE397>3.0.CO;2-3
Publication status	Published - 2001 Jan 19
Externally published	Yes

Keywords

Carbides
Cluster compounds
Fullerenes
Scandium
Structure elucidation

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/1521-3773(20010119)40:2<397::AID-ANIE397>3.0.CO;2-3

Cite this

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title = "A scandium carbide endohedral metallofullerene: (Sc2C2)@C84",

abstract = "Not Sc2@C86 but Sc2C2@C84: that is the conclusion of 13C NMR spectroscopic and synchrotron X-ray powder diffraction studies on a new metallofullerene obtained by arc discharge of Sc2O3/graphite rods. The picture shows a schematic representation of the deduced structure, in which the novel scandium carbide cluster Sc2C2 is encaged in D2d-C84.",

keywords = "Carbides, Cluster compounds, Fullerenes, Scandium, Structure elucidation",

author = "Wang, {Chun Ru} and Tsutomu Kai and Testuo Tomiyama and Takuya Yoshida and Yuji Kobayashi and Eiji Nishibori and Masaki Takata and Makoto Sakata and Hisanori Shinohara",

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T1 - A scandium carbide endohedral metallofullerene

T2 - (Sc2C2)@C84

AU - Wang, Chun Ru

AU - Kai, Tsutomu

AU - Tomiyama, Testuo

AU - Yoshida, Takuya

AU - Kobayashi, Yuji

AU - Nishibori, Eiji

AU - Takata, Masaki

AU - Sakata, Makoto

AU - Shinohara, Hisanori

PY - 2001/1/19

Y1 - 2001/1/19

N2 - Not Sc2@C86 but Sc2C2@C84: that is the conclusion of 13C NMR spectroscopic and synchrotron X-ray powder diffraction studies on a new metallofullerene obtained by arc discharge of Sc2O3/graphite rods. The picture shows a schematic representation of the deduced structure, in which the novel scandium carbide cluster Sc2C2 is encaged in D2d-C84.

AB - Not Sc2@C86 but Sc2C2@C84: that is the conclusion of 13C NMR spectroscopic and synchrotron X-ray powder diffraction studies on a new metallofullerene obtained by arc discharge of Sc2O3/graphite rods. The picture shows a schematic representation of the deduced structure, in which the novel scandium carbide cluster Sc2C2 is encaged in D2d-C84.

KW - Carbides

KW - Cluster compounds

KW - Fullerenes

KW - Scandium

KW - Structure elucidation

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