A prerequisite for purely organic molecule-based ferrimagnetics: Breakdown of simple classical pictures

Daisuke Shiomi, Masahiro Nishizawa, Kazunobu Sato, Takeji Takui, Koichi Itoh, Hiromi Sakurai, Akira Izuoka, Tadashi Sugawara

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    47 Citations (Scopus)


    Spin state energies were calculated for an antiferromagnetic linear chain composed of a doublet (S = 1/2) radical and a biradical with a triplet (S = 1) ground state by numerical diagonalization of a finite-size Heisenberg-Dirac spin Hamiltonian. A ferrimagnetic-like ground state with a spin value of S = N/2 (N stands for the number of repeating units) appears if the intermolecular antiferromagnetic exchange interactions are uniform between all the S = 1/2 sites. This finding is consistent with a simple picture of differing and neighboring spin angular moments S's ordered in sublattices in an antiparallel manner. On the other hand, quasi-degenerate low-lying states appear as the spatial symmetry of the intermolecular antiferromagnetic interactions is lowered. The quasi-degeneracy destabilizes the ferrimagnetic-like ground state. This instability is inherent in multicentered antiferromagnetic interactions between open-shell organic molecular systems, suggesting a prerequisite for long-range magnetic order in purely organic molecule-based ferrimagnetics. Such prerequisite has never been reported until now. The results of the calculations are invoked to explain the susceptibility and the spin-spin relaxation time measured for the first model system for purely organic ferrimagnetics, a nitronyl nitroxide-based molecular crystal composed of an S = 1/2 and S = 1 molecules (Izuoka, A.; Fukuda, M.; Kumai, R.; Itakura, M.; Hikami, S.; Sugawara, T. J. Am. Chem. Soc. 1994, 116, 2609-2610.).

    Original languageEnglish
    Pages (from-to)3342-3348
    Number of pages7
    JournalJournal of Physical Chemistry B
    Issue number17
    Publication statusPublished - 1997 Apr 24

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Surfaces, Coatings and Films
    • Materials Chemistry

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