A palladium-catalyzed addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes

Mieko Arisawa, Saori Tanii, Masahiko Yamaguchi

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A palladium complex derived from Pd2(dba)3 and dppp catalyzes the addition reaction of aroyl/heteroaroyl acid anhydrides to norbornenes, giving 2-aroyl/heteroaroyl-3-aroyloxy/heteroaroyloxy-bicyclo[2,2,1]heptanes. The C-O bond of acid anhydride is cleaved, and the aroyl/heteroaroyl and aroyloxy/heteroaroyloxy groups are added to alkenes. trans-Adducts are selectively obtained with the endo-benzoyl group and exo-benzoyloxy group.

Original languageEnglish
Pages (from-to)15267-15270
Number of pages4
JournalChemical Communications
Volume50
Issue number96
DOIs
Publication statusPublished - 2014 Nov 6

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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