A novel octanuclear manganese cluster with [MnII 44-O)] core

Takuya Shiga, Lingqin Han, Masayuki Nihei, Norihisa Hoshino, Tasuku Ito, Hiroki Oshio

Research output: Contribution to journalArticle

Abstract

The reaction of MnCl2·4H2O with 2-aminoethanethiol (= Haet) under anaerobic conditions afforded yellow plate crystals of octanuclear manganese complex [Mn44-O) (Mn(aet)3}4]Cl2·MeOH·4H 2O. A complex molecule consists of four fac(S)-[Mn(aet)3] units linked to MnII44-O) core by thiolato bridges. Magnetic susceptibility measurements revealed the presence of antiferromagnetic interactions through μ4-oxo and μ2-thiolato bridges.

Original languageEnglish
Pages (from-to)440-441
Number of pages2
JournalChemistry Letters
Volume35
Issue number4
DOIs
Publication statusPublished - 2006 Apr 5

ASJC Scopus subject areas

  • Chemistry(all)

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