A novel hemiporphyrazine comprising three isoindolediimine and three thiadiazole units

Nagao Kobayashi, Sayaka Inagaki, Victor N. Nemykin, Taro Nonomura

Research output: Contribution to journalArticlepeer-review

54 Citations (Scopus)

Abstract

Incorporation of the three metal ions (Ni or Cu) in the macrocyclic ring and the formation of hexamers following a 3+3 approach are novel features of the hemiporphyrazines (one example shown) formed by the condensation of 2,5-diamino-1,3,4-triazole with isoindolediimines. This is in contrast to the corresponding reaction will diaminotriazoles, which afford 2+2 products.

Original languageEnglish
Pages (from-to)2710-2712
Number of pages3
JournalAngewandte Chemie - International Edition
Volume40
Issue number14
DOIs
Publication statusPublished - 2001 Jul 16

Keywords

  • Condensation reactions
  • Heterocycles
  • Macrocycles
  • Phthalocyanines

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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