A novel carbonylative decomplexation of alkyne-dicobalt hexacarbonyls: Hyrocarbamoylation of alkynes

Takumichi Sugihara, Yoshinari Okada, Masahiko Yamaguchi, Mugio Nishizawa

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

A novel carbonylative decomplexation of alkyne-dicobalt hexacarbonyls, i.e. hydrocarbamoylation of alkynes, was carried out by reaction of the complexes with 10 equiv, of primary and secondary amines.

Original languageEnglish
Pages (from-to)768-770
Number of pages3
JournalSynlett
Issue number6
DOIs
Publication statusPublished - 1999 Jan 1

Keywords

  • Alkyne-dicobalt hexacarbonyl
  • Amine
  • Carbonylation
  • Decomplexation
  • Hydrocarbamoylation

ASJC Scopus subject areas

  • Organic Chemistry

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