A new ring expansion for a chiral hexahydroazulene skeleton possessing an angular methyl group

Masaatsu Adachi, Takema Komada, Toshio Nishikawa

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A new synthetic route for a pseudoguaiane ring system is described. The synthesis features an Ireland-Claisen rearrangement for constructing the trans-fused ring system, followed by a new ring expansion to yield a bicyclo[5.3.0]decane ring system possessing an angular methyl group.

Original languageEnglish
Pages (from-to)6942-6945
Number of pages4
JournalJournal of Organic Chemistry
Volume76
Issue number16
DOIs
Publication statusPublished - 2011 Aug 19
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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