A new organic-inorganic hybrid crystal prepared from 1-methyl-4- carbamoylpyridinium iodide and cadmium iodide

Hiroaki Kosuge; Shuji Okada; Hidetoshi Oikawa; Hachiro Nakanishi

doi:10.1080/10587250290089040

A new organic-inorganic hybrid crystal prepared from 1-methyl-4- carbamoylpyridinium iodide and cadmium iodide

Hiroaki Kosuge, Shuji Okada, Hidetoshi Oikawa, Hachiro Nakanishi

Polymer Hybrid Materials Research Center

Research output: Contribution to journal › Conference article › peer-review

3 Citations (Scopus)

Abstract

Although 4-substituted pyridinium derivatives studied so far form the 2:1 complexes with cadmium iodide, an exceptional 1:1 complex was found for 1-methyl-4-carbamoylpyridinium iodide. Its X-ray crystallographic analysis revealed that its inorganic portion has a unique structure with corner-sharing one-dimensional tetrahedral chains of (CdI₃)_n.

Original language	English
Pages (from-to)	265-268
Number of pages	4
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	377
DOIs	https://doi.org/10.1080/10587250290089040
Publication status	Published - 2002 Dec 1
Event	Proceedings of the Korea-Japan Joint Forum on Organic Materials for Electronics and Photonics (KJF2001) - Seoul, Korea, Republic of Duration: 2001 Sep 25 → 2001 Sep 27

Keywords

Pyridinium
Second-order nonlinear optics
Triiodocadmate

ASJC Scopus subject areas

Condensed Matter Physics

Access to Document

10.1080/10587250290089040

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A new organic-inorganic hybrid crystal prepared from 1-methyl-4- carbamoylpyridinium iodide and cadmium iodide. / Kosuge, Hiroaki; Okada, Shuji; Oikawa, Hidetoshi; Nakanishi, Hachiro.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 377, 01.12.2002, p. 265-268.

Research output: Contribution to journal › Conference article › peer-review

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AU - Nakanishi, Hachiro

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AB - Although 4-substituted pyridinium derivatives studied so far form the 2:1 complexes with cadmium iodide, an exceptional 1:1 complex was found for 1-methyl-4-carbamoylpyridinium iodide. Its X-ray crystallographic analysis revealed that its inorganic portion has a unique structure with corner-sharing one-dimensional tetrahedral chains of (CdI3)n.

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