A new metal-metal bonded diruthenium(II,III) compound bridged by the dianionic tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate (5-Clsalpy2-)

H. Miyasaka, C. Kachi-Terajima, T. Ishii, M. Yamashita

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

The ligand-substitution reaction of Ru2 (O2CCH3)4Cl with the tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate dianion (5-Clsalpy 2-) led to the unique diruthenium(II,III) compound [{Na(THF)2}{Ru2-(O2 CCH3)2(5-Clsalpy)2}]·THF (1·THF) which revealed the characteristic 1-D chain structure of the repeating unit [-Na-O-Ru-Ru-O-]∞ and rich redox chemistry.

Original languageEnglish
Pages (from-to)1929-1930
Number of pages2
JournalJournal of the Chemical Society, Dalton Transactions
Issue number13
DOIs
Publication statusPublished - 2001 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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