A new direct method for introducing 2-(2,4,6-tri-t-butylphenyl)-2-phosphavinylidene group. Formation of 1-phospha- and 1,3-diphospha-allenes

Masaaki Yoshifuji; Shigeru Sasaki; Naoki Inamoto

doi:10.1016/S0040-4039(01)80630-4

A new direct method for introducing 2-(2,4,6-tri-t-butylphenyl)-2-phosphavinylidene group. Formation of 1-phospha- and 1,3-diphospha-allenes

Masaaki Yoshifuji, Shigeru Sasaki, Naoki Inamoto

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

2-Phosphavinylidene group was introduced by the corresponding tri-methylsilyllithio compound toward carbonyl compounds to give 1-phosphaallenes, whereas 1,3-diphosphaallene was prepared by the reaction of 1-chloro-2-phosphavinyllithium toward a phosphinous chloride followed by dehydrochlorination.

Original language	English
Pages (from-to)	839-842
Number of pages	4
Journal	Tetrahedron Letters
Volume	30
Issue number	7
DOIs	https://doi.org/10.1016/S0040-4039(01)80630-4
Publication status	Published - 1989
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "A new direct method for introducing 2-(2,4,6-tri-t-butylphenyl)-2-phosphavinylidene group. Formation of 1-phospha- and 1,3-diphospha-allenes",

abstract = "2-Phosphavinylidene group was introduced by the corresponding tri-methylsilyllithio compound toward carbonyl compounds to give 1-phosphaallenes, whereas 1,3-diphosphaallene was prepared by the reaction of 1-chloro-2-phosphavinyllithium toward a phosphinous chloride followed by dehydrochlorination.",

author = "Masaaki Yoshifuji and Shigeru Sasaki and Naoki Inamoto",

note = "Funding Information: Further studies are in progress. This work was supported in part (No. 62540371) from the Ministry of The authors thank Shin-Etsu Chemical Co., Ltd., for donating organosilicon respectively. Copyright: Copyright 2014 Elsevier B.V., All rights reserved.",

year = "1989",

doi = "10.1016/S0040-4039(01)80630-4",

language = "English",

volume = "30",

pages = "839--842",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "7",

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TY - JOUR

T1 - A new direct method for introducing 2-(2,4,6-tri-t-butylphenyl)-2-phosphavinylidene group. Formation of 1-phospha- and 1,3-diphospha-allenes

AU - Yoshifuji, Masaaki

AU - Sasaki, Shigeru

AU - Inamoto, Naoki

N1 - Funding Information: Further studies are in progress. This work was supported in part (No. 62540371) from the Ministry of The authors thank Shin-Etsu Chemical Co., Ltd., for donating organosilicon respectively. Copyright: Copyright 2014 Elsevier B.V., All rights reserved.

PY - 1989

Y1 - 1989

N2 - 2-Phosphavinylidene group was introduced by the corresponding tri-methylsilyllithio compound toward carbonyl compounds to give 1-phosphaallenes, whereas 1,3-diphosphaallene was prepared by the reaction of 1-chloro-2-phosphavinyllithium toward a phosphinous chloride followed by dehydrochlorination.

AB - 2-Phosphavinylidene group was introduced by the corresponding tri-methylsilyllithio compound toward carbonyl compounds to give 1-phosphaallenes, whereas 1,3-diphosphaallene was prepared by the reaction of 1-chloro-2-phosphavinyllithium toward a phosphinous chloride followed by dehydrochlorination.

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U2 - 10.1016/S0040-4039(01)80630-4

DO - 10.1016/S0040-4039(01)80630-4

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AN - SCOPUS:0012304303

VL - 30

SP - 839

EP - 842

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 7

ER -

A new direct method for introducing 2-(2,4,6-tri-t-butylphenyl)-2-phosphavinylidene group. Formation of 1-phospha- and 1,3-diphospha-allenes

Abstract

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