A new convenient method for the synthesis of mixed-ligand β-diketonato Tc(III) complexes

A. Mutalib, T. Sekine, T. Omori, K. Yoshihara

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

A new convenient method has been proposed to synthesize mixed-ligand β-diketonato Tc(III) complexes, using the ligand exchange reaction [Tc(acac)2(CH3CN)2]++L-→[Tc(acac)2L]+ +2CH3CN where L is bza, dpm or dbm. The yield was about 30-40%. UV-visible and IR spectra of these complexes were measured. Characteristic features of the compounds were compared with those of the corresponding complexes of ruthenium.

Original languageEnglish
Pages (from-to)311-318
Number of pages8
JournalJournal of Radioanalytical and Nuclear Chemistry Articles
Volume178
Issue number2
DOIs
Publication statusPublished - 1994 Mar 1

ASJC Scopus subject areas

  • Analytical Chemistry
  • Nuclear Energy and Engineering
  • Radiology Nuclear Medicine and imaging
  • Pollution
  • Spectroscopy
  • Public Health, Environmental and Occupational Health
  • Health, Toxicology and Mutagenesis

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