Abstract
Treatment of 6-iodo-4-oxa-3-sila-1-hexene derivatives with arylmagnesium bromide in the presence of a catalytic amount of a cobalt-diamine complex in THF afforded the corresponding benzyl-substituted oxasilacyclopentanes in good yield. The products were converted to 4-aryl-1,3-diols after Tamao-Fleming oxidation.
Original language | English |
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Pages (from-to) | 3061-3064 |
Number of pages | 4 |
Journal | Synlett |
Issue number | 18 |
DOIs | |
Publication status | Published - 2006 Nov 3 |
Externally published | Yes |
Keywords
- 1,3-diols
- Arylation
- Cobalt
- Radical reaction
- Silicon
ASJC Scopus subject areas
- Organic Chemistry