@article{3d570814a16a4c428fc1c391a8071971,
title = "A new alkaloid taxane composed of two N-formyl rotamers from the rooted cuttings of Taxus canadensis",
abstract = "A taxane with an amino-side chain on C-5 was identified for the first time from rooted cuttings of the Canadian yew, Taxus canadensis. The structure was characterized as 2α,10β,13α-triacetoxy-5α-[3'-(N-formyl- Nmethylamino)-3'-phenylpropanoyloxy]taxa-4(20),12-dien-9α-ol (1) on the basis of 1D and 2D NMR data and HR-FAB-MS analyses. The spectra revealed that in CDCl3 solution 1 was composed of two rotamers (1a and 1b) in a ratio of approximately 1:1.",
keywords = "Taxaceae, Taxus canadensis, alkaloid, metabolites, taxane, yew",
author = "Zhang, {Hong Zhen} and Wang, {Yu Fang} and Zhang, {Man Li} and Mei Dong and Huo, {Chang Hong} and Francoise Sauriol and Shi, {Qing Wen} and Gu, {Yu Cheng} and Wang, {Hui Lan} and Hiromasa Kiyota",
note = "Funding Information: We are grateful for financial support from the National Natural Science Foundation of China (81072551), the Scientific Research Foundation for the Returning Overseas Chinese Scholars of Hebei Province (2006-02), and the Scientific Research Foundation of Hebei Province (C2010000489). We also appreciate financial support from Syngenta Ltd. (2011-Hebei Medical University-Syngenta-03) and the Japan Society for the Promotion of Science (No. 22580112).",
year = "2013",
month = jan,
doi = "10.1007/s10600-013-0458-7",
language = "English",
volume = "48",
pages = "1035--1038",
journal = "Chemistry of Natural Compounds",
issn = "0009-3130",
publisher = "Springer New York",
number = "6",
}