A neutral Pt3 stack unsupported by any bridging ligand

Lars Holland; Wei Zheng Shen; Philipp Von Grebe; Pablo J. Sanz Miguel; Fabio Pichierri; Andreas Springer; Christoph A. Schalley; Bernhard Lippert

doi:10.1039/c0dt01408g

A neutral Pt₃ stack unsupported by any bridging ligand

Lars Holland, Wei Zheng Shen, Philipp Von Grebe, Pablo J. Sanz Miguel, Fabio Pichierri, Andreas Springer, Christoph A. Schalley, Bernhard Lippert

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Pt⋯Pt⋯Pt interactions via their d⁸ orbitals, combined with π-π stacking of deprotonated, chelating 2-(3′- pyrazolyl)pyridine (pyzpy) ligands, are responsible for trans-Pt(pyzpy) ₂ (2) crystallization in a stack of three molecules unsupported by any bridging ligand.

Original language	English
Pages (from-to)	5159-5161
Number of pages	3
Journal	Dalton Transactions
Volume	40
Issue number	19
DOIs	https://doi.org/10.1039/c0dt01408g
Publication status	Published - 2011 May 21

ASJC Scopus subject areas

Inorganic Chemistry

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title = "A neutral Pt3 stack unsupported by any bridging ligand",

abstract = "Pt⋯Pt⋯Pt interactions via their d8 orbitals, combined with π-π stacking of deprotonated, chelating 2-(3′- pyrazolyl)pyridine (pyzpy) ligands, are responsible for trans-Pt(pyzpy) 2 (2) crystallization in a stack of three molecules unsupported by any bridging ligand.",

author = "Lars Holland and Shen, {Wei Zheng} and {Von Grebe}, Philipp and {Sanz Miguel}, {Pablo J.} and Fabio Pichierri and Andreas Springer and Schalley, {Christoph A.} and Bernhard Lippert",

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AU - Shen, Wei Zheng

AU - Von Grebe, Philipp

AU - Sanz Miguel, Pablo J.

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AU - Springer, Andreas

AU - Schalley, Christoph A.

AU - Lippert, Bernhard

PY - 2011/5/21

Y1 - 2011/5/21

N2 - Pt⋯Pt⋯Pt interactions via their d8 orbitals, combined with π-π stacking of deprotonated, chelating 2-(3′- pyrazolyl)pyridine (pyzpy) ligands, are responsible for trans-Pt(pyzpy) 2 (2) crystallization in a stack of three molecules unsupported by any bridging ligand.

AB - Pt⋯Pt⋯Pt interactions via their d8 orbitals, combined with π-π stacking of deprotonated, chelating 2-(3′- pyrazolyl)pyridine (pyzpy) ligands, are responsible for trans-Pt(pyzpy) 2 (2) crystallization in a stack of three molecules unsupported by any bridging ligand.

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