A Mn12 single-molecule magnet [Mn12O 12(OAc)12(dpp)4] (dppH = diphenyl phosphate) with no coordinating water molecules

Guo Qing Bian, Takayoshi Kuroda-Sowa, Hisashi Konaka, Masaki Hatano, Masahiko Maekawa, Megumu Munakata, Hitoshi Miyasaka, Masahiro Yamashita

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40 Citations (Scopus)

Abstract

The preparation and physical characterization are reported for a novel single-molecule magnet [Mn12O12(OAc)12(dpp) 4] (dppH = diphenyl phosphate) with no coordinating water molecules. The crystal structure analysis reveals that there are four five-coordinate MnIII ions with Mn⋯H approaches. Addition of water in CD 2Cl2 solution was monitored by 1H NMR, which showed that H2O could coordinate to a vacant site of a five-coordinate MnIII ion in solution. The measurements and analyses of magnetization hysteresis and ac magnetic susceptibility indicate that the title complex is a single-molecule magnet with a quantum tunneling behavior, whose ground state was tentatively assigned to S = 10 with g = 1.78 and D = -0.60 K.

Original languageEnglish
Pages (from-to)4790-4792
Number of pages3
JournalInorganic chemistry
Volume43
Issue number16
DOIs
Publication statusPublished - 2004 Aug 9
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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