A missing allene of heavy Group 14 elements: 2-Germadisilaallene

Takeaki Iwamoto; Takashi Abe; Chizuko Kabuto; Mitsuo Kira

doi:10.1039/b509878e

A missing allene of heavy Group 14 elements: 2-Germadisilaallene

Takeaki Iwamoto, Takashi Abe, Chizuko Kabuto, Mitsuo Kira

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

The first stable 2-germadisilaallene was synthesized by the reduction of a 2 : 1 mixture of a stable dialkylsilylene and dichlorogermylene-dioxane complex with KC₈; the 2-germadisilaallene showed dynamic disorder similar to the corresponding trisilaallene in the solid state.

Original language	English
Pages (from-to)	5190-5192
Number of pages	3
Journal	Chemical Communications
Issue number	41
DOIs	https://doi.org/10.1039/b509878e
Publication status	Published - 2005 Nov 7

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The first stable 2-germadisilaallene was synthesized by the reduction of a 2 : 1 mixture of a stable dialkylsilylene and dichlorogermylene-dioxane complex with KC8; the 2-germadisilaallene showed dynamic disorder similar to the corresponding trisilaallene in the solid state.",

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AU - Kira, Mitsuo

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AB - The first stable 2-germadisilaallene was synthesized by the reduction of a 2 : 1 mixture of a stable dialkylsilylene and dichlorogermylene-dioxane complex with KC8; the 2-germadisilaallene showed dynamic disorder similar to the corresponding trisilaallene in the solid state.

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A missing allene of heavy Group 14 elements: 2-Germadisilaallene

Abstract

ASJC Scopus subject areas

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