A microchip capillary electrophoretic reactor: A new methodology for direct measurement of dissociation kinetics of metal complexes

Toru Takahashi; Kei Ichirou Ohtsuka; Nobuhiko Iki; Hitoshi Hoshino

doi:10.1039/b509546h

A microchip capillary electrophoretic reactor: A new methodology for direct measurement of dissociation kinetics of metal complexes

Toru Takahashi, Kei Ichirou Ohtsuka, Nobuhiko Iki, Hitoshi Hoshino

ENV - Frontier Science for Advanced Environment

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A microchip capillary electrophoretic reactor has been proposed and successfully demonstrated in the direct evaluation of the solvolytic dissociation rate constant of the complex of Ce³⁺ with a polyaminocarboxylic ligand, 8-amino-2-[(2-amino-5-methylphentixyl)methyl]-6- methoxyquinoline-N,N,N′,N′-tetraacetic acid.

Original language	English
Pages (from-to)	1337-1339
Number of pages	3
Journal	Analyst
Volume	130
Issue number	10
DOIs	https://doi.org/10.1039/b509546h
Publication status	Published - 2005 Oct

ASJC Scopus subject areas

Analytical Chemistry
Biochemistry
Environmental Chemistry
Spectroscopy
Electrochemistry

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abstract = "A microchip capillary electrophoretic reactor has been proposed and successfully demonstrated in the direct evaluation of the solvolytic dissociation rate constant of the complex of Ce3+ with a polyaminocarboxylic ligand, 8-amino-2-[(2-amino-5-methylphentixyl)methyl]-6- methoxyquinoline-N,N,N′,N′-tetraacetic acid.",

author = "Toru Takahashi and Ohtsuka, {Kei Ichirou} and Nobuhiko Iki and Hitoshi Hoshino",

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AU - Takahashi, Toru

AU - Ohtsuka, Kei Ichirou

AU - Iki, Nobuhiko

AU - Hoshino, Hitoshi

PY - 2005/10

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N2 - A microchip capillary electrophoretic reactor has been proposed and successfully demonstrated in the direct evaluation of the solvolytic dissociation rate constant of the complex of Ce3+ with a polyaminocarboxylic ligand, 8-amino-2-[(2-amino-5-methylphentixyl)methyl]-6- methoxyquinoline-N,N,N′,N′-tetraacetic acid.

AB - A microchip capillary electrophoretic reactor has been proposed and successfully demonstrated in the direct evaluation of the solvolytic dissociation rate constant of the complex of Ce3+ with a polyaminocarboxylic ligand, 8-amino-2-[(2-amino-5-methylphentixyl)methyl]-6- methoxyquinoline-N,N,N′,N′-tetraacetic acid.

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A microchip capillary electrophoretic reactor: A new methodology for direct measurement of dissociation kinetics of metal complexes

Abstract

ASJC Scopus subject areas

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