A luminescent single-molecule magnet: Observation of magnetic anisotropy using emission as a probe

Kei Yamashita, Rie Miyazaki, Yumiko Kataoka, Takayuki Nakanishi, Yasuchika Hasegawa, Motohiro Nakano, Tomoo Yamamura, Takashi Kajiwara

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

An assemblage of a Tb(iii) ion and two mononuclear [ZnII(L)] complexes as antenna chromophores (H2L: Schiff base ligand) afforded a luminescent single-molecule magnet. The f-f emission spectrum had partially resolved fine structure which provides detailed information on the magnetic anisotropy of the 7F6 ground multiplet of the Tb(iii) ion.

Original languageEnglish
Pages (from-to)1987-1990
Number of pages4
JournalDalton Transactions
Volume42
Issue number6
DOIs
Publication statusPublished - 2013 Feb 14

ASJC Scopus subject areas

  • Inorganic Chemistry

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    Yamashita, K., Miyazaki, R., Kataoka, Y., Nakanishi, T., Hasegawa, Y., Nakano, M., Yamamura, T., & Kajiwara, T. (2013). A luminescent single-molecule magnet: Observation of magnetic anisotropy using emission as a probe. Dalton Transactions, 42(6), 1987-1990. https://doi.org/10.1039/c2dt32785f