Abstract
Single-molecule magnets: A cyanide-bridged hexanuclear complex showed a thermal electron-transfer-coupled spin transition centered at 220a K. Light irradiation at low temperature (LT; HT=high temperature) generated a metastable state showing slow magnetic relaxation in measurements of the alternating-current magnetic susceptibility (Ï m; see picture).
Original language | English |
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Pages (from-to) | 6361-6364 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 51 |
Issue number | 26 |
DOIs | |
Publication status | Published - 2012 Jun 25 |
Externally published | Yes |
Keywords
- cobalt
- cyanides
- heterometallic complexes
- iron
- mixed-valent compounds
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)