A light-induced phase exhibiting slow magnetic relaxation in a cyanide-bridged [Fe 4Co 2] complex

Masayuki Nihei; Yuki Okamoto; Yoshihiro Sekine; Norihisa Hoshino; Takuya Shiga; Isiah Po Chun Liu; Hiroki Oshio

doi:10.1002/anie.201202225

A light-induced phase exhibiting slow magnetic relaxation in a cyanide-bridged [Fe ₄Co ₂] complex

Masayuki Nihei, Yuki Okamoto, Yoshihiro Sekine, Norihisa Hoshino, Takuya Shiga, Isiah Po Chun Liu, Hiroki Oshio

Research output: Contribution to journal › Article › peer-review

97 Citations (Scopus)

Abstract

Single-molecule magnets: A cyanide-bridged hexanuclear complex showed a thermal electron-transfer-coupled spin transition centered at 220a K. Light irradiation at low temperature (LT; HT=high temperature) generated a metastable state showing slow magnetic relaxation in measurements of the alternating-current magnetic susceptibility (Ï _m; see picture).

Original language	English
Pages (from-to)	6361-6364
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	26
DOIs	https://doi.org/10.1002/anie.201202225
Publication status	Published - 2012 Jun 25
Externally published	Yes

Keywords

cobalt
cyanides
heterometallic complexes
iron
mixed-valent compounds

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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A light-induced phase exhibiting slow magnetic relaxation in a cyanide-bridged [Fe ₄Co ₂] complex. / Nihei, Masayuki; Okamoto, Yuki; Sekine, Yoshihiro ; Hoshino, Norihisa; Shiga, Takuya; Liu, Isiah Po Chun; Oshio, Hiroki.

In: Angewandte Chemie - International Edition, Vol. 51, No. 26, 25.06.2012, p. 6361-6364.

Research output: Contribution to journal › Article › peer-review

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AU - Shiga, Takuya

AU - Liu, Isiah Po Chun

AU - Oshio, Hiroki

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KW - heterometallic complexes

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