A ladder polysilane wrapped with amylose

Nobu Kato, Takanobu Sanji, Masato Tanaka, Tetsuya Fukasawa, Shintaro Ishida, Soichiro Kyushin

Research output: Contribution to journalShort surveypeer-review

2 Citations (Scopus)

Abstract

A mixture of tricyclic ladder polysilane 1 and amylose, upon pH adjustment of aqueous media from very basic to neutral, affords a supramolecular complex in which a preferential twisted (helical) conformation is induced on the ladder polysilane to display optical activity. Under the experimental conditions used, 1 assumes a left-handed twisted structure in the left-handed helical channel of amylose.

Original languageEnglish
Pages (from-to)3212-3214
Number of pages3
JournalJournal of Organometallic Chemistry
Volume694
Issue number19
DOIs
Publication statusPublished - 2009 Sep 1
Externally publishedYes

Keywords

  • Amylose
  • Chirality
  • Cotton effect
  • Ladder
  • Polysilane

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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