A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: A polymorph of the hexagonal 2-D network phase

Natsuko Motokawa; Tomomi Oyama; Satoshi Matsunaga; Hitoshi Miyasaka; Kunihisa Sugimoto; Masahiro Yamashita; Nazario Lopez; Kim R. Dunbar

doi:10.1039/b808503j

A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: A polymorph of the hexagonal 2-D network phase

Natsuko Motokawa, Tomomi Oyama, Satoshi Matsunaga, Hitoshi Miyasaka, Kunihisa Sugimoto, Masahiro Yamashita, Nazario Lopez, Kim R. Dunbar

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

The slow diffusion reaction of [Ru₂(O₂CCF ₃)₄(THF)₂] with TCNQ in CH₂Cl ₂/4-chlorotoluene, respectively, leads to the formation of ladder chain composed of [Ru₂] rails and TCNQ rungs in a 2 : 1 ratio.

Original language	English
Pages (from-to)	4099-4102
Number of pages	4
Journal	Dalton Transactions
Issue number	31
DOIs	https://doi.org/10.1039/b808503j
Publication status	Published - 2008 Aug 15

ASJC Scopus subject areas

Inorganic Chemistry

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A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs : A polymorph of the hexagonal 2-D network phase. / Motokawa, Natsuko; Oyama, Tomomi; Matsunaga, Satoshi; Miyasaka, Hitoshi; Sugimoto, Kunihisa; Yamashita, Masahiro; Lopez, Nazario; Dunbar, Kim R.

In: Dalton Transactions, No. 31, 15.08.2008, p. 4099-4102.

Research output: Contribution to journal › Article › peer-review

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abstract = "The slow diffusion reaction of [Ru2(O2CCF 3)4(THF)2] with TCNQ in CH2Cl 2/4-chlorotoluene, respectively, leads to the formation of ladder chain composed of [Ru2] rails and TCNQ rungs in a 2 : 1 ratio.",

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AU - Yamashita, Masahiro

AU - Lopez, Nazario

AU - Dunbar, Kim R.

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AB - The slow diffusion reaction of [Ru2(O2CCF 3)4(THF)2] with TCNQ in CH2Cl 2/4-chlorotoluene, respectively, leads to the formation of ladder chain composed of [Ru2] rails and TCNQ rungs in a 2 : 1 ratio.

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A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: A polymorph of the hexagonal 2-D network phase

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