A highly enantioselective and catalytic aryl transfer reaction using mixed triarylbismuthane and dialkylzinc reagents

Itaru Sato; Yousuke Toyota; Noriaki Asakura

doi:10.1002/ejoc.200700212

A highly enantioselective and catalytic aryl transfer reaction using mixed triarylbismuthane and dialkylzinc reagents

Itaru Sato, Yousuke Toyota, Noriaki Asakura

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Highly enantioselective and catalytic aryl transfer reactions to aromatic aldehydes by using mixed triarylbismuthane and dimethylzinc reagents were studied. In the presence of a chiral β-amino alcohol catalyst, chiral diarylmethanols with up to 97 % ee were obtained.

Original language	English
Pages (from-to)	2608-2610
Number of pages	3
Journal	European Journal of Organic Chemistry
Issue number	16
DOIs	https://doi.org/10.1002/ejoc.200700212
Publication status	Published - 2007 Jun 22

Keywords

Arylation
Asymmetric synthesis
Bismuth
Catalysis
Zinc

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry

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10.1002/ejoc.200700212

Cite this

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title = "A highly enantioselective and catalytic aryl transfer reaction using mixed triarylbismuthane and dialkylzinc reagents",

abstract = "Highly enantioselective and catalytic aryl transfer reactions to aromatic aldehydes by using mixed triarylbismuthane and dimethylzinc reagents were studied. In the presence of a chiral β-amino alcohol catalyst, chiral diarylmethanols with up to 97 % ee were obtained.",

keywords = "Arylation, Asymmetric synthesis, Bismuth, Catalysis, Zinc",

author = "Itaru Sato and Yousuke Toyota and Noriaki Asakura",

year = "2007",

month = jun,

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doi = "10.1002/ejoc.200700212",

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T1 - A highly enantioselective and catalytic aryl transfer reaction using mixed triarylbismuthane and dialkylzinc reagents

AU - Sato, Itaru

AU - Toyota, Yousuke

AU - Asakura, Noriaki

PY - 2007/6/22

Y1 - 2007/6/22

N2 - Highly enantioselective and catalytic aryl transfer reactions to aromatic aldehydes by using mixed triarylbismuthane and dimethylzinc reagents were studied. In the presence of a chiral β-amino alcohol catalyst, chiral diarylmethanols with up to 97 % ee were obtained.

AB - Highly enantioselective and catalytic aryl transfer reactions to aromatic aldehydes by using mixed triarylbismuthane and dimethylzinc reagents were studied. In the presence of a chiral β-amino alcohol catalyst, chiral diarylmethanols with up to 97 % ee were obtained.

KW - Arylation

KW - Asymmetric synthesis

KW - Bismuth

KW - Catalysis

KW - Zinc

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DO - 10.1002/ejoc.200700212

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JF - Annalen der Pharmacie

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ER -

A highly enantioselective and catalytic aryl transfer reaction using mixed triarylbismuthane and dialkylzinc reagents

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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