A highly enantioselective and catalytic aryl transfer reaction using mixed triarylbismuthane and dialkylzinc reagents

Itaru Sato, Yousuke Toyota, Noriaki Asakura

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Highly enantioselective and catalytic aryl transfer reactions to aromatic aldehydes by using mixed triarylbismuthane and dimethylzinc reagents were studied. In the presence of a chiral β-amino alcohol catalyst, chiral diarylmethanols with up to 97 % ee were obtained.

Original languageEnglish
Pages (from-to)2608-2610
Number of pages3
JournalEuropean Journal of Organic Chemistry
Issue number16
DOIs
Publication statusPublished - 2007 Jun 22

Keywords

  • Arylation
  • Asymmetric synthesis
  • Bismuth
  • Catalysis
  • Zinc

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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