A Ferromagnetically Coupled Octanuclear Manganese(III) Cluster: A Single-Molecule Magnet with a Spin Ground State of S = 16

Takuya Shiga, Hiroyuki Nojiri, Hiroki Oshio

Research output: Contribution to journalArticle

Abstract

An octanuclear manganese complex, [MnIII8(μ4-O)4(L)4(OMe)4(OAc)4(OCH2CH2NH3)4] [1; H2L = 3-(dimethoxymethyl)-2-hydroxybenzoic acid], was synthesized with an extended cubane core structure consisting of eight Mn ions bridged by O atoms. Cryomagnetic studies revealed that 1 showed a single-molecule-magnet behavior with an S = 16 spin ground state.

Original languageEnglish
Pages (from-to)4163-4166
Number of pages4
JournalInorganic chemistry
Volume59
Issue number7
DOIs
Publication statusPublished - 2020 Apr 6

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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